In addition to high levels of oxygen,
the crude steel tapped from the converter also contains
impurities which are not desired in the final steel chemistry;
the steelmaking process relies on raw
materials from a number of sources such as iron ore,
coke,
limestone
and recycled steel scrap. These materials contain impurities
which when added to the steelmaking process inevitably result
in low levels of elements not desired in the final steel
chemistry being found in the steel.
Modern primary and secondary steelmaking practices can reduce the
level of these impurities to a very low level, but usually
a residual impurity level remains. One of the trace elements
that is present during the steel making process and is generally
undesirable is sulphur. The presence of free sulphur in
a steel product is detrimental to its properties, especially
toughness.
Modern steel making processes and selection of raw materials means
that the levels of sulphur present in a steel are very low.
Any remaining sulphur can be removed through the use of
alloying
additions of manganese which reacts with the sulphur to
form MnS. MnS inclusions are relatively soft, especially
at elevated temperature, and can become elongated during
hot rolling,
forging or drawing processing, (see types
of inclusions).
The presence of elongated MnS inclusions in the rolled / forged
/ drawn steel can present a problem for the manufacturing
/ fabrication / finishing stage of steel processing. This
is especially true for strip steels that are going to be
deep drawn into drinks cans. The reason for this is that
the deep drawing process occurs at room temperature where
the MnS inclusions are no longer soft enough to deform.
As the steel blank is drawn into the can shape the wall
thickness of the can is reduced to ~6 µm. MnS inclusions
can be several micron in length and this can cause failure
of the can through tearing. Any increase in can reject number
will cost the manufacturer in terms of time retrieving the
damaged can and revenue for the rejected can. This means
that rejects from inclusions cannot be tolerated and extremely
clean steels are required. This is achieved through precise
control of the steel making stage of processing to ensure
that there are virtually no MnS inclusions present in the
steel destined to be strip steel used for making drinks
cans. Also additions can be made to the steel which modify
any MnS inclusions present to a composition which remains
globular and does not deform to give long MnS stringers
during steel rolling. Due to the increased costs associated
with specifying such high levels of cleanness
for this product grade of steel, other less stringent product
grades are not specified to such a high level and MnS inclusions
will be seen (although at a low level due to the general
level of steel cleanness achievable today).