A
concise mathematical description of the relationship between
the real and reciprocal lattice vectors is given by:
Where V is the volume of the real
lattice cell and is given vectorially by: V= a . b
Ù c
| These equations show that: |
a* is perpendicular
to both b and c |
|
b* is
perpendicular to both c
and a |
|
c* is
perpendicular to both a
and b |
These equations also enable you to calculate the length of the reciprocal vectors.
However, same relationships can be expressed in other ways and the following vector
relationships are also true:
|
a* . b = a* . c
= 0 |
i.e. a* is
perpendicular to both b
and c |
|
b* . a = b* . c = 0 |
i.e. b* is
perpendicular to both c
and a |
|
c* . a = c* . b = 0 |
i.e. c* is
perpendicular to both a
and b |
Another way of stating the relationships is:
| These equations show that: |
a* is
perpendicular to the (100) plane |
|
b* is
perpendicular to the (010) plane |
|
c* is
perpendicular to the (001) plane |
Note: the reciprocal vector a*
is always perpendicular to the plane (100) (since the (100) plane contains the b and c vectors) but the real lattice
vector a might not be,
depending on the crystal system. The vector a
is always perpendicular to the (100) for the cubic system.
It is also true that : a*
. a = b* . b = c* . c = 1
These equations give the magnitudes of the reciprocal vectors. Note that |a*| = 1 / |a|
only for orthogonal lattices (e.g. cubic, tetragonal and orthorhombic).
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